SW levels description and walkthrough:

PC Eurocorp PC Church PC levels list PSX levels list Unguided levs

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Levels in PC and PSX versions of Syndicate Wars are different, but very similar. Some of them are identical. Some missions are in different cities, but has same objectives. Others are nearly identical, only 2 or 3 buildings are different.

On PSX version, there's more "horizonal elevators", while on PC, you can find many IML trains. Also, there are no white scientist people on PSX - they look like suitcase man.

You can view levels from campaings, or see the full list of all levels available.